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Complete analysis of materials for preparing alumina ceramic structural components: scientific formula from raw materials to finished products

Update time:2018-04-12

In the field of high-end manufacturing, alumina ceramics have become a core material in strategic industries such as semiconductor equipment, new energy batteries, and biomedicine due to their excellent mechanical strength, high-temperature resistance, and chemical stability. This article will systematically analyze the key material systems and their mechanism of action in the preparation process of alumina ceramic structural components.

I. Matrix Materials: Classification and Application of Alumina Powder

Industrial-grade alumina (92-95% purity)

Characteristics: Optimal cost-performance ratio, Vickers hardness ≥ 1200

Typical applications:

• Ceramic scrapers for lithium battery separator coating machines

• Guide wheels for photovoltaic silicon wafer cutting

• Mechanical seal rings for chemical pumps

High-purity alumina (99-99.6% purity)

Characteristics: Dielectric strength > 15kV/mm, thermal conductivity 30W/(m·K)

Typical applications:

• Semiconductor wafer transfer robotic arms

• 5G filter ceramic substrates

• Medical dental implants

Ultra-high-purity alumina (99.9%-99.99% purity)

Characteristics: Surface roughness up to Ra < 0.1μm

Cutting-edge applications:

• Ceramic workpiece tables for integrated circuit lithography machines

• Collimators for proton therapy equipment

• Microwave wave-transparent windows for spacecraft

II. Modified Additive Systems

Sintering aid systems

MgO-CaO-SiO₂ system: Through the liquid-phase sintering mechanism, the sintering temperature can be reduced to 1500°C

Rare earth oxide composite system (Y₂O₃+La₂O₃): Realizes grain boundary engineering regulation, and the fracture toughness is increased by 40%

Functional modifiers

ZrO₂ toughening: Phase transformation toughening makes the KIC value reach 6.5MPa·m¹/²

SiC whisker reinforcement: Flexural strength increased to 650MPa

CNT composite: Friction coefficient reduced to below 0.15

III. Forming and Processing Auxiliary Materials

Advanced binder systems

Aqueous gel system: Suitable for 3D printing forming

Thermoplastic resin system: Used for micro-injection molding (μPIM)

Photosensitive resin system: Meets the requirements of DLP forming process

Precision processing consumables

Diamond grinding fluid: Particle size distribution 0.1-1μm

CMP polishing fluid: SiO₂@CeO₂ core-shell structure abrasives

Laser processing gas: SF₆-assisted laser micro-hole processing

IV. Key Materials for Quality Control

Testing reference materials

Alumina crystal phase standards (α/θ/κ phases)

Fluorescent penetrants for surface defect detection

Coating and sintering materials

High-purity zirconia embedding powder: Prevents contamination during high-temperature sintering

Boron nitride isolating agent: Avoids interlayer bonding

Current technological frontiers:

Low-temperature sintering technology of nanocrystalline alumina powder (particle size < 50nm)

Multilayer gradient ceramic co-firing technology (LTCC/HTCC)

Optical functionalization treatment of transparent oxide ceramics

With the development of new material technologies, alumina ceramics are evolving towards multi-functionality, integration, and intelligence. From raw material proportioning to microstructural control, the precise regulation of each material link directly affects the performance of the final product, which requires collaborative innovation between material scientists and process engineers.

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