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In the field of high-end manufacturing, alumina ceramics have become a core material in strategic industries such as semiconductor equipment, new energy batteries, and biomedicine due to their excellent mechanical strength, high-temperature resistance, and chemical stability. This article will systematically analyze the key material systems and their mechanism of action in the preparation process of alumina ceramic structural components.
I. Matrix Materials: Classification and Application of Alumina Powder
Industrial-grade alumina (92-95% purity)
Characteristics: Optimal cost-performance ratio, Vickers hardness ≥ 1200
Typical applications:
• Ceramic scrapers for lithium battery separator coating machines
• Guide wheels for photovoltaic silicon wafer cutting
• Mechanical seal rings for chemical pumps
High-purity alumina (99-99.6% purity)
Characteristics: Dielectric strength > 15kV/mm, thermal conductivity 30W/(m·K)
Typical applications:
• Semiconductor wafer transfer robotic arms
• 5G filter ceramic substrates
• Medical dental implants
Ultra-high-purity alumina (99.9%-99.99% purity)
Characteristics: Surface roughness up to Ra < 0.1μm
Cutting-edge applications:
• Ceramic workpiece tables for integrated circuit lithography machines
• Collimators for proton therapy equipment
• Microwave wave-transparent windows for spacecraft
II. Modified Additive Systems
Sintering aid systems
MgO-CaO-SiO₂ system: Through the liquid-phase sintering mechanism, the sintering temperature can be reduced to 1500°C
Rare earth oxide composite system (Y₂O₃+La₂O₃): Realizes grain boundary engineering regulation, and the fracture toughness is increased by 40%
Functional modifiers
ZrO₂ toughening: Phase transformation toughening makes the KIC value reach 6.5MPa·m¹/²
SiC whisker reinforcement: Flexural strength increased to 650MPa
CNT composite: Friction coefficient reduced to below 0.15
III. Forming and Processing Auxiliary Materials
Advanced binder systems
Aqueous gel system: Suitable for 3D printing forming
Thermoplastic resin system: Used for micro-injection molding (μPIM)
Photosensitive resin system: Meets the requirements of DLP forming process
Precision processing consumables
Diamond grinding fluid: Particle size distribution 0.1-1μm
CMP polishing fluid: SiO₂@CeO₂ core-shell structure abrasives
Laser processing gas: SF₆-assisted laser micro-hole processing
IV. Key Materials for Quality Control
Testing reference materials
Alumina crystal phase standards (α/θ/κ phases)
Fluorescent penetrants for surface defect detection
Coating and sintering materials
High-purity zirconia embedding powder: Prevents contamination during high-temperature sintering
Boron nitride isolating agent: Avoids interlayer bonding
Current technological frontiers:
Low-temperature sintering technology of nanocrystalline alumina powder (particle size < 50nm)
Multilayer gradient ceramic co-firing technology (LTCC/HTCC)
Optical functionalization treatment of transparent oxide ceramics
With the development of new material technologies, alumina ceramics are evolving towards multi-functionality, integration, and intelligence. From raw material proportioning to microstructural control, the precise regulation of each material link directly affects the performance of the final product, which requires collaborative innovation between material scientists and process engineers.